The links to the full text of publications can be added to the references in the URL or DOI field.
Such a link is often included when you import references from bibliographical databases.
Use the button Attachments + to add a File, Linked File or Web Link (PDF, Word, Excel etc.) which you saved on your own PC.
The added file is also included in C:Users>U/S/E/Z-number>Zotero>storage.
From within Zotero you can also search whether a full text of a reference in your library can be found on the internet.
To achieve this you have to adjust some settings once-only via Edit – Settings – General
Now you can have Zotero search the internet for the full text of a reference in your library.
Select reference(s) in the short title list and click right-mouse-button and select Find Full Text.
The Find Full Text screen appears and show if Full Text is succesful added as an attachment (a paperclip icon will appear).